As far as I know it's not possible with Active Record's built-in enum functionality. However, there are a few popular 3rd party gems that do this. The closest match to what comes with Active Record are probably enumerize and SimpleEnum.
However, if you're looking for something a little different, I'd recommend ClassyEnum (full disclosure: I wrote it). Here are some of my notes on the difference between enumerize and SimpleEnum vs ClassyEnum:
Class-less enums (enumerize, SimpleEnum) are great for simple use
cases where you just need a field to represent one of a fixed set of
values. The main issue I have with this solution is that it encourages
conditionals scattered throughout your models, controllers and views.
It's tempting to use these gems because they are the simplest to
implement, but the long term payoff just isn't there IMO for anything
but the simplest cases.
ClassyEnum was designed to solve the problem of having scattered
conditional logic related to the different enums. You can still use it
for simple collections that don't have logic, but when you do need to
add logic (and you almost certainly will), you can push that into the
individual enum classes and take advantage of polymorphism.